Structural investigation and hydrogen capacity of CaMg2Ni9:: a new phase in the AB2C9 system isostructural with LaMg2Ni9

被引：191

作者：

Kadir, K

Kuriyama, N

Sakai, T

Uehara, I

Eriksson, L

机构：

[1] Dept Energy & Environm, Osaka Natl Res Inst, Ikeda, Osaka 5638577, Japan

[2] Univ Stockholm, Arrhenius Lab, Dept Struct Chem, S-10691 Stockholm, Sweden

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1999年 / 284卷 / 1-2期

关键词：

hydrogen storage alloy; X-ray diffraction; neutron diffraction; thermal analysis; pressure-composition isotherms; electrochemical; crystal structure;

D O I：

10.1016/S0925-8388(98)00965-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new ternary magnesium-based alloy CaMg2Ni9 has been synthesized, and its crystal structure was determined by Guinier-Hagg X-ray and neutron powder diffraction, The compound has a hexagonal structure and is isostructural with LaMg2Ni9 type, with Ca at the La atom site. The hydrogen absorption/desorption properties have been determined by thermal analysis and pressure-composition isotherms. The electrochemical properties of the alloy were also examined. (C) 1999 Elsevier Science BN. All rights reserved.

引用

页码：145 / 154

页数：10

共 34 条

[11] CRYSTAL-STRUCTURE OF A NEW STACKING VARIANT OF A FRIAUF-LAVES PHASE IN SYSTEM MG-CU-NI [J].