A novel strategy for making soluble reduced graphene oxide sheets cheaply by adopting an endogenous reducing agent

被引:204
作者
Ai, Kelong [1 ]
Liu, Yanlan [1 ,2 ]
Lu, Lehui [1 ]
Cheng, Xiaoli [3 ]
Huo, Lihua [3 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Elect Chem, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
[3] Heilongjiang Univ, Harbin 150080, Peoples R China
关键词
SOLID-STATE NMR; GRAPHITE OXIDE; EXFOLIATED GRAPHITE; ORGANIC-SOLVENTS; NITRIC-OXIDE; DISPERSIONS; REDUCTION; ELECTRONICS; NANOSHEETS; COMPOSITE;
D O I
10.1039/c0jm02865g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A facile and efficient strategy is described for the fabrication of soluble reduced graphene oxide (rGO) sheets. Different from the conventional strategies, the proposed method is based on the reduction of graphene oxide by an endogenous reducing agent from a most widely used and cost-effective solvent, without adding any other toxic reducing agent. Simultaneously, this solvent can serve as an effective stabilizer, avoiding complicated and time-consuming modification procedures. The as-prepared rGO sheets not only exhibit high reduction level and conductivity, but also can be well dispersed in many solvents. Of particular significance is that rGO sheets can be produced in large quantities. These advantages endow this proposed synthetic approach great potential applications in the construction of high-performance graphene-based devices at low cost, as demonstrated in our study of NO gas sensing.
引用
收藏
页码:3365 / 3370
页数:6
相关论文
共 55 条
[41]   Conjugated-Polyelectrolyte-Functionalized Reduced Graphene Oxide with Excellent Solubility and Stability in Polar Solvents [J].
Qi, Xiaoying ;
Pu, Kan-Yi ;
Zhou, Xiaozhu ;
Li, Hai ;
Liu, Bin ;
Boey, Freddy ;
Huang, Wei ;
Zhang, Hua .
SMALL, 2010, 6 (05) :663-669
[42]   Graphene: The New Two-Dimensional Nanomaterial [J].
Rao, C. N. R. ;
Sood, A. K. ;
Subrahmanyam, K. S. ;
Govindaraj, A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (42) :7752-7777
[43]   Detection of individual gas molecules adsorbed on graphene [J].
Schedin, F. ;
Geim, A. K. ;
Morozov, S. V. ;
Hill, E. W. ;
Blake, P. ;
Katsnelson, M. I. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (09) :652-655
[44]   Graphene-based composite materials [J].
Stankovich, Sasha ;
Dikin, Dmitriy A. ;
Dommett, Geoffrey H. B. ;
Kohlhaas, Kevin M. ;
Zimney, Eric J. ;
Stach, Eric A. ;
Piner, Richard D. ;
Nguyen, SonBinh T. ;
Ruoff, Rodney S. .
NATURE, 2006, 442 (7100) :282-286
[45]   High-throughput solution processing of large-scale graphene [J].
Tung, Vincent C. ;
Allen, Matthew J. ;
Yang, Yang ;
Kaner, Richard B. .
NATURE NANOTECHNOLOGY, 2009, 4 (01) :25-29
[46]   Dimethylformamide as a carbon monoxide source in fast palladium-catalyzed aminocarbonylations of aryl bromides [J].
Wan, YQ ;
Alterman, M ;
Larhed, M ;
Hallberg, A .
JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (17) :6232-6235
[47]   Synthesis of Graphene Aerogel with High Electrical Conductivity [J].
Worsley, Marcus A. ;
Pauzauskie, Peter J. ;
Olson, Tammy Y. ;
Biener, Juergen ;
Satcher, Joe H., Jr. ;
Baumann, Theodore F. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (40) :14067-14069
[48]   Graphenes as potential material for electronics [J].
Wu, Jishan ;
Pisula, Wojciech ;
Muellen, Klaus .
CHEMICAL REVIEWS, 2007, 107 (03) :718-747
[49]   Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets [J].
Xu, Yuxi ;
Bai, Hua ;
Lu, Gewu ;
Li, Chun ;
Shi, Gaoquan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (18) :5856-+
[50]  
Yamada T, 2002, ADV MATER, V14, P812, DOI 10.1002/1521-4095(20020605)14:11<812::AID-ADMA812>3.0.CO