Facile incorporation of Platinum(IV) into polyoxometalate frameworks:: Preparation of [H2PtIVV9O28]5- and characterization by 195Pt NMR spectroscopy

被引：79

作者：

Lee, Uk ^{[1
]}

Joo, Hea-Chung ^{[3
]}

Park, Ki-Min ^{[4
]}

Mal, Sib Sankar ^{[2
]}

Kortz, Ulrich ^{[2
]}

Keita, Bineta ^{[5
]}

Nadjo, Louis ^{[5
]}

机构：

[1] Pukyong Natl Univ, Dept Chem, Pusan 608737, South Korea

[2] Jacobs Univ Bremen, Sch Engn Sci, D-28725 Bremen, Germany

[3] Dong Eui Univ, Dept Chem, Pusan 614714, South Korea

[4] Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 660701, South Korea

[5] Univ Paris 11, CNRS, UMR 8000, Chim Phys Lab, F-91405 Orsay, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 04期

关键词：

inorganic synthesis; NMR spectroscopy; platinum; polyoxometalates; X-ray diffraction;

D O I：

10.1002/anie.200703082

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A new mate for vanadate: The platinum (IV)-containing polyoxovanadate [H2PtIVV9O28] 5- (1) has been synthesized and structurally characterized (see polyhedral representation). The characterization of polyanion 1 in solution by 195Pt NMR spectroscopy is unprecedented in POM chemistry. The facile synthetic procedure with the PtIV precursor H2Pt(OH) 6 appears to be a convenient and general methodology for making a large variety of PtIV-containing polyoxometalates. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：793 / 796

页数：4

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