A unique 3D alternating ferro- and antiferromagnetic manganese azide system with threefold interpenetrating (10,3) nets

被引:96
作者
Liu, CM [1 ]
Gao, S
Zhang, DQ
Huang, YH
Xiong, RG
Liu, ZL
Jiang, FC
Zhu, DB
机构
[1] Chinese Acad Sci, Inst Chem, Organ Solids Lab, Ctr Mol Sci, Beijing 100080, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat & Applicat, Beijing 100871, Peoples R China
[3] Jiangxi Normal Univ, Dept Chem, Nanchang 330027, Peoples R China
[4] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
关键词
azides; interpenetrating nets; magnetic properties; manganese; solvothermal reactions;
D O I
10.1002/anie.200352780
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Alternative bridging: Alternating ferro- and antiferromagnetic interactions are mediated by alternating end-on and end-to-end azido bridges, respectively, in a novel manganese azido complex. The compound has an interesting framework of threefold interpenetrating (10,3) nets, one of which is shown in the picture.
引用
收藏
页码:990 / 994
页数:5
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