Reduction reactions using a binuclear palladium complex catalyst precursor and di-tert-butyl peroxide

被引：10

作者：

Cho, IS ^{[1
]}

Alper, H ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 106卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会;

关键词：

binuclear complexes; palladium; selectivity; hydrogenation; alpha; beta-Unsaturated compounds; carbonyls; sulfones; phosphonates; butyl peroxide;

D O I：

10.1016/1381-1169(95)00198-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The binuclear palladium complex, [(Bu(2)(t)PH)PdPBu(2)(t)](2), preactivated by treatment with di-tert-butyl peroxide, catalyzes the selective hydrogenation of the carbon-carbon double bond of alpha,beta-unsaturated carbonyls, sulfones and phosphonates in THF at room temperature and 1 atm of hydrogen pressure.

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收藏

页码：7 / 10

页数：4

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