MILD REDUCTION OF ALPHA,BETA-UNSATURATED KETONES AND ALDEHYDES WITH AN OXYGEN-ACTIVATED PALLADIUM CATALYST

被引:29
作者
SOMMOVIGO, M [1 ]
ALPER, H [1 ]
机构
[1] UNIV OTTAWA,OTTAWA CARLETON CHEM INST,DEPT CHEM,OTTAWA K1N 6N5,ONTARIO,CANADA
关键词
D O I
10.1016/S0040-4039(00)60057-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reaction of the binuclear palladium complex, [(R2PH)PdPR2]2, where R=t-Bu, with oxygen gives a very efficient catalyst for the hydrogenation of alpha,beta-unsaturated carbonyls.
引用
收藏
页码:59 / 62
页数:4
相关论文
共 14 条
[1]   SELECTIVE REDUCTION OF CONJUGATED DOUBLE-BONDS WITH MOLECULAR-HYDROGEN AND PALLADIUM(II) COMPLEXED TO FERROCENYLAMINE SULFIDE CATALYSTS [J].
ALI, HM ;
NAIINI, AA ;
BRUBAKER, CH .
TETRAHEDRON LETTERS, 1991, 32 (40) :5489-5492
[2]  
[Anonymous], 1985, HYDROGENATION METHOD
[3]  
BRETENSKY DM, 1989, TETRAHEDRON LETT, V30, P5677
[4]  
Colquhoun H.M., 1984, NEW PATHWAYS ORGANIC
[5]   SELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES IN AQUEOUS ORGANIC 2-PHASE SOLVENT SYSTEMS USING RUTHENIUM OR RHODIUM COMPLEXES OF SULFONATED PHOSPHINES [J].
GROSSELIN, JM ;
MERCIER, C ;
ALLMANG, G ;
GRASS, F .
ORGANOMETALLICS, 1991, 10 (07) :2126-2133
[6]   CHEMOSPECIFIC, BIPHASIC REDUCTION OF ALPHA,BETA-UNSATURATED ALDEHYDES AND KETONES CATALYZED BY (CY3P)2RH(H)CL2 [J].
GRUSHIN, VV ;
ALPER, H .
ORGANOMETALLICS, 1991, 10 (04) :831-833
[8]  
James B. R., 1973, HOMOGENEOUS HYDROGEN
[9]   CONJUGATE REDUCTION OF POLYFUNCTIONAL ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS USING [(PH3P)CUH]6 - COMPATIBILITY WITH HALOGEN, SULFONATE, AND GAMMA-OXYGEN AND SULFUR SUBSTITUENTS [J].
KOENIG, TM ;
DAEUBLE, JF ;
BRESTENSKY, DM ;
STRYKER, JM .
TETRAHEDRON LETTERS, 1990, 31 (23) :3237-3240
[10]  
Larock R.C., 1989, COMPREHENSIVE ORGANI