Meso-aryl-β-pyrrolic positions interactions in meso-tetraarylporphyrins.: Flat arylporphyrins and building blocks for oligoporphyrins

被引：18

作者：

Callot, HJ ^{[1
]}

Ruppert, R ^{[1
]}

Jeandon, C ^{[1
]}

Richeter, S ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, UMR 7123, Fac Chim, F-67000 Strasbourg, France

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2004年 / 8卷 / 1-3期

关键词：

porphyrins; meso-aryl groups; acylation; chelating substituents; oligoporphyrins;

D O I：

10.1142/S1088424604000106

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aryl groups bound to the meso positions of porphyrins often react with neighboring groups, in particular beta-acyl groups to give highly diversified monomeric and dimeric new functionalized porphyrins. The products, whose meso-aryl ring approaches coplanarity with the porphyrin macrocycle, show large shifts of UV-visible absorption bands and various potentialities for building external chelating moieties and assembling oligoporphyrins. Copyright (c) 2004 Society of Porphyrins & Phthalocyanines.

引用

页码：111 / 119

页数：9

共 46 条

[31] Preparation of six isomeric bis-acylporphyrins with chromophores reaching the near-infrared via intramolecular Friedel-Crafts reaction [J].

Richeter, S ;

Jeandon, C ;

Kyritsakas, N ;

Ruppert, R ;

Callot, HJ .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (24) :9200-9208

[32] Syntheses and optical and electrochemical properties of porphyrin dimers linked by metal ions [J].

Richeter, S ;

Jeandon, C ;

Gisselbrecht, JP ;

Ruppert, R ;

Callot, HJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (21) :6168-6179

[33] Reactivity of oxonaphtoporphyrins.: Efficient β-functionalization of the porphyrin ring on reaction with nitrogen or carbon nucleophiles [J].

Richeter, S ;

Jeandon, C ;

Ruppert, R ;

Callot, HJ .

TETRAHEDRON LETTERS, 2001, 42 (11) :2103-2106

[34] Porphyrins acting as external and internal ligands: preparation of conjugated trimetallic dimeric porphyrins [J].

Richeter, S ;

Jeandon, C ;

Ruppert, R ;

Callot, HJ .

CHEMICAL COMMUNICATIONS, 2001, (01) :91-92

[35]

RICHETER S, 2003, THESIS U LOUIS PASTE

[36] Reaction of β-formylporphyrins with organometallic reagents -: A facile method for the preparation of porphyrins with exocyclic double bonds [J].

Runge, S ;

Senge, MO .

TETRAHEDRON, 1999, 55 (34) :10375-10390

[37]

Sanders JKM, 2000, PORPHYRIN HDB, V3, P347

[38] STRUCTURAL STUDIES OF 1,8-DISUBSTITUTED NAPHTHALENES AS PROBES FOR NUCLEOPHILE-ELECTROPHILE INTERACTIONS [J].

SCHWEIZER, WB ;

PROCTER, G ;

KAFTORY, M ;

DUNITZ, JD .

HELVETICA CHIMICA ACTA, 1978, 61 (08) :2783-2808

[39]

Senge M. O., 2000, PORPHYRIN HDB, V1, P239

[40] Synthesis of chlorins possessing a fused naphthalene ring [J].

Sengupta, D ;

Robinson, BC .

TETRAHEDRON, 2002, 58 (27) :5497-5502

← 1 2 3 4 5 →