Effects of substituents on the photochemical and photophysical properties of main group metal phthalocyanines

被引:706
作者
Nyokong, Tebello [1 ]
机构
[1] Rhodes Univ, Dept Chem, ZA-6139 Grahamstown, South Africa
基金
新加坡国家研究基金会;
关键词
metallophthalocyanine; triplet state quantum yield; triplet lifetimes; fluorescence quantum yield; photobleaching;
D O I
10.1016/j.ccr.2006.11.011
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The review focuses on the photochemical (singlet oxygen and photobleaching quantum yields) and photophysical (triplet quantum yields and lifetimes and fluorescence lifetimes) properties of metallophthalocyanine complexes containing main group metals (Zn, Al, Ge, Si, Sn, Ga and In) and some unmetallated phthalocyanine complexes. Five tables containing photophysical and photochemical data for sulfonated phthalocyanines, tetra-, octa-substituted and unsubstituted phthalocyanines in a variety of solvents, are included in the review. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:1707 / 1722
页数:16
相关论文
共 126 条
[51]   Photophysical properties of metal complexes of meso-tetrakis(4-sulphonatophenyl)porphyrin [J].
Kubat, P ;
Mosinger, J .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1996, 96 (1-3) :93-97
[52]   Sulfonated phthalocyanines: aggregation and singlet oxygen quantum yield in aqueous solutions [J].
Kuznetsova, NA ;
Gretsova, NS ;
Derkacheva, VM ;
Kaliya, OL ;
Lukyanets, EA .
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2003, 7 (03) :147-154
[53]   Generation of singlet oxygen with anionic aluminum phthalocyanines in water [J].
Kuznetsova, NA ;
Gretsova, NS ;
Derkacheva, VM ;
Mikhalenko, SA ;
Solov'eva, LI ;
Yuzhakova, OA ;
Kaliya, OL ;
Luk'yanets, EA .
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2002, 72 (02) :300-306
[54]  
Kuznetsova NA, 2000, RUSS J GEN CHEM, V70, P133
[55]   Photophysical studies of some 5,10,15,20-tetraarylethynylporphyrinatozinc(II) complexes as potential lead compounds for photodynamic therapy [J].
Lacey, JA ;
Phillips, D ;
Milgrom, LR ;
Yahioglu, G ;
Rees, RD .
PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1998, 67 (01) :97-100
[56]   THE ROLE OF EXCITED-STATES IN THE PHOTOSENSITIZED OXIDATION OF SUBSTRATES WITH DIOXYGEN [J].
LANG, K ;
WAGNEROVA, DM ;
BRODILOVA, J .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1993, 72 (01) :9-14
[57]   QUENCHING OF THE TRIPLET-STATE OF METALLOPHTHALOCYANINES BY DIOXYGEN IN THE PRESENCE OF BOVINE SERUM-ALBUMIN [J].
LANG, K ;
WAGNEROVA, DM ;
ENGST, P ;
KUBAT, P .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 1994, 187 :213-221
[58]  
Leznoff C.C., 1989, PHTHALOCYANINES PROP, V1
[59]   Phthalocyanines part I A new type of synthetic colouring matters [J].
Linstead, RP .
JOURNAL OF THE CHEMICAL SOCIETY, 1934, :1016-1017
[60]  
Lukyanets EA, 1999, J PORPHYR PHTHALOCYA, V3, P424, DOI 10.1002/(SICI)1099-1409(199908/10)3:6/7<424::AID-JPP151>3.3.CO