[TmIII(hfac)3(NITPhOPh)]∞:: A new member of a lanthanide-based single chain magnets family

被引：97

作者：

Bernot, K.

Bogani, L.

Sessoli, R.

Gatteschi, D.

机构：

[1] Univ Stud Firenze, Dept Chem & INSTM, I-50019 Sesto Fiorentino, Italy

[2] INSA Rennes, UMR 6226 CNRS, Sci Chimniques Rennes, F-35043 Rennes, France

来源：

INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 13期

关键词：

nitronyl-nitroxides; single chain magnets; lanthanides; magnetic anisotropy;

D O I：

10.1016/j.ica.2006.12.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The polymeric coordination compound of formula [Tm(hfaC)(3)(NITPhOPh)](infinity) (where NITPhOPh is a nitronyl-nitroxide radical) has been synthesized and found to belong to the only reported family of isostructural Single Chain Magnets. Both static and dynamic magnetic measurements have been performed, and a dependence of the out-of-phase signal on the frequency is observed below 3 K. Scaling procedures indicate Ising magnetic anisotropy. Comparison of the extracted parameters with those of the previously reported isostructural compounds confirms a trend along the lanthanide series. (c) 2006 Elsevier B.V. All rights reserved.

引用

收藏

页码：3807 / 3812

页数：6

相关论文

共 36 条

[1]

Abragam A., 1986, ELECT PARAMAGNETIC R

[2] Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals [J].

Benelli, C ;

Gatteschi, D .

CHEMICAL REVIEWS, 2002, 102 (06) :2369-2387

[3] LINEAR-CHAIN GADOLINIUM(III) NITRONYL NITROXIDE COMPLEXES WITH DOMINANT NEXT-NEAREST-NEIGHBOR MAGNETIC-INTERACTIONS [J].

BENELLI, C ;

CANESCHI, A ;

GATTESCHI, D ;

PARDI, L ;

REY, P .

INORGANIC CHEMISTRY, 1990, 29 (21) :4223-4228

[4] MAGNETIC-PROPERTIES AND PHASE-TRANSITIONS IN MOLECULAR BASED MATERIALS CONTAINING RARE-EARTH IONS AND ORGANIC RADICALS [J].

BENELLI, C ;

CANESCHI, A ;

GATTESCHI, D ;

SESSOLI, R .

JOURNAL OF APPLIED PHYSICS, 1993, 73 (10) :5333-5337

[5] MAGNETIC-INTERACTIONS AND MAGNETIC-ORDERING IN RARE-EARTH-METAL NITRONYL NITROXIDE CHAINS [J].

BENELLI, C ;

CANESCHI, A ;

GATTESCHI, D ;

SESSOLI, R .

INORGANIC CHEMISTRY, 1993, 32 (22) :4797-4801

[6] A family of rare-earth-based single chain magnets: Playing with anisotropy [J].

Bernot, Kevin ;

Bogani, Lapo ;

Caneschi, Andrea ;

Gatteschi, Dante ;

Sessoli, Roberta .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (24) :7947-7956

[7] Finite-size effects on the static properties of a single-chain magnet [J].

Bogani, L ;

Sessoli, R ;

Pini, MG ;

Rettori, A ;

Novak, MA ;

Rosa, P ;

Massi, M ;

Fedi, ME ;

Giuntini, L ;

Caneschi, A ;

Gatteschi, D .

PHYSICAL REVIEW B, 2005, 72 (06)

[8] Finite-size effects in single chain magnets: An experimental and theoretical study [J].

Bogani, L ;

Caneschi, A ;

Fedi, M ;

Gatteschi, D ;

Massi, M ;

Novak, MA ;

Pini, MG ;

Rettori, A ;

Sessoli, R ;

Vindigni, A .

PHYSICAL REVIEW LETTERS, 2004, 92 (20) :207204-1

[9] Molecular engineering for single-chain-magnet behavior in a one-dimensional dysprosium-nitronyl nitroxide compound [J].

Bogani, L ;

Sangregorio, C ;

Sessoli, R ;

Gatteschi, D .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (36) :5817-5821

[10] THE CHEMISTRY AND MAGNETIC-PROPERTIES OF METAL NITRONYL NITROXIDE COMPLEXES [J].

CANESCHI, A ;

GATTESCHI, D ;

REY, P .

PROGRESS IN INORGANIC CHEMISTRY, 1991, 39 :331-429

← 1 2 3 4 →