Chiral rhodium(II,II) dimers catalyzed enantioselective intramolecular aziridination of sulfonamides and carbamates

被引：85

作者：

Liang, JL

Yuan, SX

Chan, PWH

Che, CM

机构：

[1] Univ Hong Kong, Inst Mol Technol Drug Discovery & Synth, Dept Chem, Hong Kong, Hong Kong, Peoples R China

[2] Univ Hong Kong, Inst Mol Technol Drug Discovery & Synth, Open Lab Chem Biol, Hong Kong, Hong Kong, Peoples R China

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 31期

关键词：

D O I：

10.1016/S0040-4039(03)01409-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The asymmetric intramolecular aziridination of unsaturated sulfonamides and carbamates catalyzed by chiral dirhodium(11,11) complexes were achieved in good yields (up to 95%) and enantioselectivity (up to 76% e.e.). (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：5917 / 5920

页数：4

共 46 条

[1]

ANDO T, 1998, TETRAHEDRON LETT, V39, P4715

[2] Amidation of unfunctionalized hydrocarbons catalyzed by ruthenium cyclic amine or bipyridine complexes [J].