Chiral rhodium(II,II) dimers catalyzed enantioselective intramolecular aziridination of sulfonamides and carbamates

被引：85

作者：

Liang, JL

Yuan, SX

Chan, PWH

Che, CM

机构：

[1] Univ Hong Kong, Inst Mol Technol Drug Discovery & Synth, Dept Chem, Hong Kong, Hong Kong, Peoples R China

[2] Univ Hong Kong, Inst Mol Technol Drug Discovery & Synth, Open Lab Chem Biol, Hong Kong, Hong Kong, Peoples R China

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 31期

关键词：

D O I：

10.1016/S0040-4039(03)01409-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The asymmetric intramolecular aziridination of unsaturated sulfonamides and carbamates catalyzed by chiral dirhodium(11,11) complexes were achieved in good yields (up to 95%) and enantioselectivity (up to 76% e.e.). (C) 2003 Elsevier Ltd. All rights reserved.

引用

收藏

页码：5917 / 5920

页数：4

相关论文

共 46 条

[21] Enantioselective aziridination using copper complexes of biaryl Schiff bases [J].

Gillespie, KM ;

Sanders, CJ ;

O'Shaughnessy, P ;

Westmoreland, I ;

Thickitt, CP ;

Scott, P .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (10) :3450-3458

[22] Mn(salen)-catalyzed enantioselective C-H amination [J].

Kohmura, Y ;

Katsuki, T .

TETRAHEDRON LETTERS, 2001, 42 (19) :3339-3342

[23] Amidoglycosylation via metal-catalyzed internal nitrogen atom delivery [J].

Levites-Agababa, E ;

Menhaji, E ;

Perlson, LN ;

Rojas, CM .

ORGANIC LETTERS, 2002, 4 (05) :863-865

[24] ASYMMETRIC ALKENE AZIRIDINATION WITH READILY AVAILABLE CHIRAL DIIMINE-BASED CATALYSTS [J].

LI, Z ;

CONSER, KR ;

JACOBSEN, EN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (12) :5326-5327

[25] Rhodium(II,II) dimer as an efficient catalyst for aziridination of sulfonamides and amidation of steroids [J].

Liang, JL ;

Yuan, SX ;

Chan, PWH ;

Che, CM .

ORGANIC LETTERS, 2002, 4 (25) :4507-4510

[26] Amidation of silyl enol ethers and cholesteryl acetates with chiral ruthenium(II) Schiff-base catalysts: catalytic and enantioselective studies [J].

Liang, JL ;

Yu, XQ ;

Che, CM .

CHEMICAL COMMUNICATIONS, 2002, (02) :124-125

[27]

Liang JL, 2002, ANGEW CHEM INT EDIT, V41, P3465, DOI 10.1002/1521-3773(20020916)41:18<3465::AID-ANIE3465>3.0.CO

[28]

2-D

[29]

Liang JL, 2002, CHEM-EUR J, V8, P1563, DOI 10.1002/1521-3765(20020402)8:7<1563::AID-CHEM1563>3.0.CO

[30]

2-V

← 1 2 3 4 5 →