A comparative study of an MCM-41 anchored quaternary ammonium chloride/SnCl4 catalyst and its silica gel analogue

被引:30
作者
Jyothi, TM [1 ]
Kaliya, ML [1 ]
Herskowitz, M [1 ]
Landau, MV [1 ]
机构
[1] Ben Gurion Univ Negev, Dept Chem Engn, Blechner Ctr Ind Catalysis & Proc Dev, IL-84105 Beer Sheva, Israel
关键词
D O I
10.1039/b101843o
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel reusable Lewis acid catalyst has been prepared by the heterogenization of a Lewis acid/tetrapropylammonium adduct; anchoring of tin chloride on quaternary ammonium chloride functionalized MCM-41 yielded a catalyst with higher activity compared to the corresponding silica analogue in terms of turnover rates and product yield in the Prins condensation of isobutene and formaldehyde to isoprenol.
引用
收藏
页码:992 / 993
页数:2
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