Aqueous Colloidal Mesoporous Nanoparticles with Ethenylene-Bridged Silsesquioxane Frameworks

被引:191
作者
Urata, Chihiro [3 ]
Yamada, Hironori [3 ]
Wakabayashi, Ryutaro [3 ,4 ]
Aoyama, Yuko [3 ]
Hirosawa, Shota [1 ]
Arai, Satoshi [2 ]
Takeoka, Shinji [1 ]
Yamauchi, Yusuke [5 ,6 ]
Kuroda, Kazuyuki [3 ,4 ]
机构
[1] Waseda Univ, Fac Sci & Engn, Dept Life Sci & Med Biosci, Tokyo, Japan
[2] Waseda Univ, Comprehens Res Org, Tokyo, Japan
[3] Waseda Univ, Dept Appl Chem, Fac Sci & Engn, Tokyo 169, Japan
[4] Waseda Univ, Kagami Mem Res Inst Mat Sci & Technol, Tokyo, Japan
[5] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton MANA, World Premier Int WPI Res Ctr, Tsukuba, Ibaraki 3050047, Japan
[6] Japan Sci & Technol Agcy JST, Precursory Res Embryon Sci & Technol PRESTO, Tokyo, Japan
关键词
SILICA NANOPARTICLES; HEMOLYTIC-ACTIVITY; DEGRADATION; IMPACT; SIZE;
D O I
10.1021/ja201779d
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Aqueous colloidal mesoporous nanoparticles with ethenylene-bridged silsesquioxane frameworks with a uniform diameter of similar to 20 nm were prepared from bis(triethoxysilyl)ethenylene in a basic aqueous solution containing cationic surfactants. The nanopartides, which had higher hydrolysis resistance under aqueous conditions, showed lower hemolytic activity toward bovine red blood cells than colloidal mesoporous silica nanoparticles.
引用
收藏
页码:8102 / 8105
页数:4
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