Ionic liquids as a recyclable reaction medium for the Baylis-Hillman reaction

被引：148

作者：

Rosa, JN ^{[1
]}

Afonso, CAM ^{[1
]}

Santos, AG ^{[1
]}

机构：

[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, Ctr Quim Fina & Biotecnol, Dept Quim, P-2825114 Monte De Caparica, Portugal

来源：

TETRAHEDRON | 2001年 / 57卷 / 19期

关键词：

D O I：

10.1016/S0040-4020(01)00316-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Baylis-Hillman reaction using 1,4-diazabicyclo[2.2.2]octane (DABCO) has been shown to be 33.6 times faster in the recyclable ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]) than in acetonitrile. Low yields (14-20%) of adducts an obtained from aliphatic aldehydes and moderate to high yields (39-72%) from aromatic aldehydes. Recycling and reuse of the reaction medium was demonstrated. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：4189 / 4193

页数：5

共 46 条

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