Thickness-shear mode acoustic sensor for atrazine using molecularly imprinted polymer as recognition element

被引:38
作者
Luo, CH [1 ]
Liu, MQ [1 ]
Mo, YC [1 ]
Qu, JN [1 ]
Feng, YL [1 ]
机构
[1] Hengyang Normal Coll, Dept Chem, Hengyang 421008, Hunan, Peoples R China
关键词
TSM acoustic sensor; atrazine; molecularly imprinted polymer; recognition element;
D O I
10.1016/S0003-2670(00)01216-2
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A new thickness-shear mode (TSM) acoustic sensor for the determination of atrazine was fabricated using a molecularly imprinted polymer (MIP) as recognition element. The influence of functional monomers on sensor response was investigated. The experiment conditions such as pH and the amount of coating were optimized. The sensor showed high sensitivity and selectivity to the template atrazine. At the range of concentrations detected, the relationship between the frequency shift (-Deltaf) and log(C) was obtained with a polynomial fitting programme. The determination limit was 2.0 x 10(-6) mol/l. This method seems to be applicable for the development of mass sensor, combining the advantages of both biological receptors and synthetic imprinted polymers. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:143 / 148
页数:6
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