Reaction between isocyanides and dialkyl acetylenedicarboxylates in the presence of 4,5-diphenyl-1,3-dihydro-2H-imidazol-2-one.: One-pot synthesis of 5H-imidazo[2,1-b][1,3]oxazine derivatives

被引:33
作者
Adib, M
Ghanbary, K
Mostofi, M
Bijanzadeh, HR
机构
[1] Univ Tehran, Dept Chem, Fac Sci, Tehran, Iran
[2] Tarbiat Modares Univ, Dept Chem, Tehran, Iran
关键词
isocyanides; acetylenic esters; 4,5-diphenyl-1,3-dihydro-2H-imidazol-2-one; three-component reactions; 2,3-diphenyl-5H-imidazo[2,1-b[1,3]oxazines;
D O I
10.1016/j.tet.2005.01.056
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reactive 1: 1 intermediate produced in the reaction between alkyl or aryl isocyanides and dialkyl acetylenedicarboxylates was trapped by 4,5-diphenyl-1,3-dihydro-2H-imidazol-2-one to yield highly functionalized 2,3-diphenyl-5H-imidazo[2,1-b][1,3]oxazine derivatives in fairly good yields. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2645 / 2648
页数:4
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