Crystal engineering of an inclusion coordination polymer with cationic pocket-like structure and its property to form metal-organic nanofibers

被引：48

作者：

Lu, JY

Norman, C

Abboud, KA

Ison, A

机构：

[1] Univ Houston Clear Lake, Dept Chem, Houston, TX 77058 USA

[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 09期

基金：

美国国家科学基金会;

关键词：

coordination polymer; cationic structure; hydrothermal reactions; electrospinning; nanofiber; 4,4 '-bipyridine;

D O I：

10.1016/S1387-7003(01)00248-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of cobalt nitrate hexahydrate with 4,4 ' -bipyridine (BPY) under hydrothermal conditions produced a new cationic pocket-like coordination polymer built by mixed double-hydrogen-bonded and coordinated 4,4 ' -bipyridine rectangular-grid with inclusion species, and this material has been fabricated into metal-organic nanofibers by electrospinning. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：459 / 461

页数：3

共 13 条

[1] Rectangular grid two-dimensional sheets of copper(II) bridged by both co-ordinated and hydrogen bonded 4,4'-bipyridine (4,4'-bipy) in [Cu(mu-4,4'-bipy)(H2O)(2)(FBF3)(2)]center dot 4,4'-bipy [J].