Fabrication of amorphous mixed-valent molybdenum oxide film electrodepo sited on a glassy carbon electrode and its application as a electrochemistry sensor of iodate

被引：33

作者：

Tian, L ^{[1
]}

Liu, L ^{[1
]}

Chen, L ^{[1
]}

Lu, N ^{[1
]}

Xu, HD ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2005年 / 105卷 / 02期

关键词：

amorphous mixed-valent molybdenum; electrodeposition; iodate; electrocatalytic;

D O I：

10.1016/j.snb.2004.07.007

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

novel amorphous mixed-valent molybdenum oxide film was grown on a glassy carbon by the electrodepositing method. Its electrochemical behaviors were studied by cyclic voltammetry and amperometry. It exhibited a high stability and electrocatalytic activity for the reduction of iodate. Amperometry revealed a good linear relationship between peak current with the concentration of iodate in the range of 1 x 10(-6) and 2 x 10(-4) mol L-1 with a correlation coefficient of 0.9997 and the detection limit of 5 x 10(-7) mol L-1 (signalmoise, = 3: 1). (c) 2004 Elsevier B.V. All rights reserved.

引用

页码：484 / 489

页数：6

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