Facile Mechanosynthesis of Amorphous Zeolitic Imidazolate Frameworks

被引：189

作者：

Bennett, Thomas D. ^{[1
]}

Cao, Shuai ^{[1
]}

Tan, Jin Chong ^{[1
]}

Keen, David A. ^{[2
]}

Bithell, Erica G. ^{[1
]}

Beldon, Patrick J. ^{[3
]}

Friscic, Tomislav ^{[3
]}

Cheetham, Anthony K. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England

[2] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England

[3] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 37期

基金：

英国工程与自然科学研究理事会;

关键词：

MECHANICAL-PROPERTIES; CRYSTAL-STRUCTURES; PORE-SIZE; PRESSURE; TEMPERATURE; DIFFRACTION; SEPARATION;

D O I：

10.1021/ja206082s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A fast and efficient mechanosynthesis (ball-milling) method of preparing amorphous zeolitic imidazolate frameworks (ZIFs) from different starting materials is discussed. Using X-ray total scattering, N-2 sorption analysis, and gas pycnometry, these frameworks are indistinguishable from one another and from temperature-amorphized ZIFs. Gas sorption analysis also confirms that they are nonporous once formed, in contrast to activated ZIF-4, which displays interesting gate-opening behavior. Nanoparticles of a prototypical nanoporous substituted ZIF, ZIF-8, were also prepared and shown to undergo amorphization.

引用

页码：14546 / 14549

页数：4

共 25 条

[21] The silica-like extended polymorphism of cobalt(II) imidazolate three-dimensional frameworks: X-ray single-crystal structures and magnetic properties [J].

Tian, YQ ;

Cai, CX ;

Ren, XM ;

Duan, CY ;

Xu, Y ;

Gao, S ;

You, XZ .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (22) :5673-5685

[22] Design and generation of extended zeolitic metal-organic frameworks (ZMOFs): Synthesis and crystal structures of zinc(II) imidazolate polymers with zeolitic topologies [J].

Tian, Yun-Qi ;

Zhao, Yu-Ming ;

Chen, Zhen-Xia ;

Zhang, Guang-Ning ;

Weng, Lin-Hong ;

Zhao, Dong-Yuan .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (15) :4146-4154

[23] Real and reciprocal space structural correlations contributing to the first sharp diffraction peak in silica glass [J].

Uchino, T ;

Harrop, JD ;

Taraskin, SN ;

Elliott, SR .

PHYSICAL REVIEW B, 2005, 71 (01)

[24] Highly Permeable Zeolite Imidazolate Framework-8 Membranes for CO2/CH4 Separation [J].

Venna, Surendar R. ;

Carreon, Moises A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) :76-+

[25] Catalytic oxidation of aromatic oxygenates by the heterogeneous catalyst Co-ZIF-9 [J].

Zakzeski, Joseph ;

Debczak, Agnieszka ;

Bruijnincx, Pieter C. A. ;

Weckhuysen, Bert M. .

APPLIED CATALYSIS A-GENERAL, 2011, 394 (1-2) :79-85

← 1 2 3 →