Solution-Processed Metallic Conducting Polymer Films as Transparent Electrode of Optoelectronic Devices

被引：976

作者：

Xia, Yijie ^{[1
]}

Sun, Kuan ^{[1
]}

Ouyang, Jianyong ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Mat & Engn, Singapore 117574, Singapore

来源：

ADVANCED MATERIALS | 2012年 / 24卷 / 18期

关键词：

PEDOT:PSS; conducting polymer; polymer solar cells; transparent electrode; conductivity; POLY(3,4-ETHYLENE DIOXYTHIOPHENE)-POLY(STYRENE SULFONATE); LIGHT-EMITTING-DIODES; CARBON NANOTUBE FILMS; ELECTRICAL-CONDUCTIVITY; SOLAR-CELLS; THIN-FILMS; POLY(STYRENESULFONATE) FILMS; ENHANCED CONDUCTIVITY; GRAPHENE OXIDE; PSS FILMS;

D O I：

10.1002/adma.201104795

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The conductivity of PEDOT:PSS films was significantly enhanced from 0.3 S cm(-1) to 3065 S cm(-1) through a treatment with dilute sulfuric acids. PEDOT: PSS films with a sheet resistance of 39 O sq(-1) and transparency of around 80% at 550 nm are obtained. These PEDOT: PSS films with conductivity and transparency comparable to ITO can replace ITO as the transparent electrode of optoelectronic devices.

引用

页码：2436 / 2440

页数：5

共 53 条

[1] The first truly all-polymer electrochromic devices [J].

Argun, AA ;

Cirpan, A ;

Reynolds, JR .

ADVANCED MATERIALS, 2003, 15 (16) :1338-+

[2] Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].

Becerril, Hdctor A. ;

Mao, Jie ;

Liu, Zunfeng ;

Stoltenberg, Randall M. ;

Bao, Zhenan ;

Chen, Yongsheng .

ACS NANO, 2008, 2 (03) :463-470

[3] Polymer light-emitting diodes with polyethylene dioxythiophene-polystyrene sulfonate as the transparent anode [J].

Cao, Y ;

Yu, G ;

Zhang, C ;

Menon, R ;

Heeger, AJ .

SYNTHETIC METALS, 1997, 87 (02) :171-174

[4] Polymer solar cells with poly(3,4-ethylenedioxythiophene) as transparent anode [J].

Chang, Yi-Ming ;

Wang, Leeyih ;

Su, Wei-Fang .

ORGANIC ELECTRONICS, 2008, 9 (06) :968-973

[5] A commodity no more [J].

Chipman, Andrea .

NATURE, 2007, 449 (7159) :131-131

[6] The origin of the high conductivity of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS) plastic electrodes [J].

Crispin, X. ;

Jakobsson, F. L. E. ;

Crispin, A. ;

Grim, P. C. M. ;

Andersson, P. ;

Volodin, A. ;

van Haesendonck, C. ;

Van der Auweraer, M. ;

Salaneck, W. R. ;

Berggren, M. .

CHEMISTRY OF MATERIALS, 2006, 18 (18) :4354-4360

[7] Conductivity, morphology, interfacial chemistry, and stability of poly(3,4-ethylene dioxythiophene)-poly(styrene sulfonate): A photoelectron spectroscopy study [J].

Crispin, X ;

Marciniak, S ;

Osikowicz, W ;

Zotti, G ;

Van der Gon, AWD ;

Louwet, F ;

Fahlman, M ;

Groenendaal, L ;

De Schryver, F ;

Salaneck, WR .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2003, 41 (21) :2561-2583

[8] Influence of a water rinse on the structure and properties of poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) films [J].

DeLongchamp, DM ;

Vogt, BD ;

Brooks, CM ;

Kano, K ;

Obrzut, J ;

Richter, CA ;

Kirillov, OA ;

Lin, EK .

LANGMUIR, 2005, 21 (24) :11480-11483

[9] Influence of ionic liquids on the electrical conductivity and morphology of PEDOT:PSS films [J].

Dobbelin, Markus ;

Marcilla, Rebeca ;

Salsamendi, Maitane ;

Pozo-Gonzalo, Cristina ;

Carrasco, Pedro M. ;

Pomposo, Jose A. ;

Mecerreyes, David .

CHEMISTRY OF MATERIALS, 2007, 19 (09) :2147-2149

[10] Significant conductivity enhancement of conductive poly(3,4-ethylenedioxythiophene): Poly(styrenesulfonate) films by adding anionic surfactants into polymer solution [J].

Fan, Benhu ;

Mei, Xiaoguang ;

Ouyang, Jianyong .

MACROMOLECULES, 2008, 41 (16) :5971-5973

← 1 2 3 4 5 6 →