Synthesis and properties of a stable, cationic, rhodium Lewis-acid catalyst for hydrosilation, Mukaiyama aldol and cyclopropanation reactions

被引：46

作者：

Dias, EL ^{[1
]}

Brookhart, M ^{[1
]}

White, PS ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 05期

关键词：

D O I：

10.1039/b007815h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The remarkably stable cationic, three-coordinate, 14-electron rhodium complex 1 has been synthesized, isolated and used as a catalyst for hydrosilation, Mukaiyama aldol and cyclopropanation reactions.

引用

页码：423 / 424

页数：2

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