Boronic acid building blocks: tools for sensing and separation

被引：378

作者：

Nishiyabu, Ryuhei ^{[2
]}

Kubo, Yuji ^{[2
]}

James, Tony D. ^{[1
]}

Fossey, John S. ^{[2
,3
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Tokyo Metropolitan Univ, Grad Sch Urban Environm Sci, Dept Appl Chem, Tokyo 1920397, Japan

[3] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 04期

关键词：

ASSISTED CARBOHYDRATE ELECTROPHORESIS; BIDENTATE LEWIS-ACID; FLUORIDE-ION; PHENYLBORONIC ACID; FLUORESCENT CHEMOSENSORS; AFFINITY-CHROMATOGRAPHY; SYNTHETIC RECEPTORS; GLUCOSE DETECTION; SUBSTITUTED VIOLOGENS; MOLECULAR RECOGNITION;

D O I：

10.1039/c0cc02920c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this feature article the use of boronic acids to monitor, identify and isolate analytes within physiological, environmental and industrial scenarios is discussed. Boronic acids recognise diol motifs through boronic ester formation and interact with anions generating boronates, as such they have been exploited in sensing and separation protocols for diol appended molecules such as saccharides and anions alike. Therefore robust molecular sensors with the capacity to detect chosen molecules selectively and signal their presence continues to attract substantial attention, and boronic acids have been exploited with some success to monitor the presence of various analytes. Reversible boronic acid-diol interactions have also been exploited in boron affinity chromatography realising new separation domains through the same binding events. Boronic acid diol and anion interactions pertaining to sensing and separation are surveyed.

引用

页码：1106 / 1123

页数：18

共 233 条

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