Synthesis of seven-membered-ring ketones by arylative ring expansion of alkyne-substituted cyclobutanones

被引：85

作者：

Matsuda, T ^{[1
]}

Makino, M ^{[1
]}

Murakami, M ^{[1
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 29期

关键词：

rhodium; boron; elimination; ketones; ring expansion;

D O I：

10.1002/anie.200500799

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Ever-increasing circles: Seven-membered-ring ketones are constructed by a rhodium(I)-catalyzed arylative ring-expansion reaction of alkyne-substituted aryl cyclobutanones, in which two C-C bond-forming and one C-C bond-cleaving events occur consecutively (see scheme). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4608 / 4611

页数：4

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