A stereoselective enyne cross metathesis

被引:71
作者
Lee, HY
Kim, BG
Snapper, ML
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem, Ctr Mol Design & Synth, Taejon, South Korea
[2] Korea Adv Inst Sci & Technol, Sch Mol Sci, Taejon, South Korea
[3] Boston Coll, Dept Chem, Merkert Chem Ctr, Chestnut Hill, MA 02467 USA
关键词
D O I
10.1021/ol034408n
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Intermolecular enyne metathesis reaction of alkynes with olefins catalyzed by second-generation Grubbs catalyst (1) proceeded stereoselectively under ethylene atmosphere to produce 1,3-disubstituted buladienes with E stereochemistry.
引用
收藏
页码:1855 / 1858
页数:4
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