A carbene-stabilized gold(I) fluoride:: Synthesis and theory

被引：120

作者：

Laitar, DS

Müller, P

Gray, TG

Sadighi, JP

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

[2] Case Western Reserve Univ, Cleveland, OH 44106 USA

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 19期

关键词：

D O I：

10.1021/om050619f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first isolable gold(I) fluoride complex, stabilized by an N-heterocyclic carbene (NHC) ligand, has been isolated in two-coordinate monomeric form. DFT calculations show significant p pi/d pi interactions between fluoride and gold(I) and indicate a substantial negative charge on fluorine.

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收藏

页码：4503 / 4505

页数：3

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