A solid solution approach to 2D coordination polymers for CH4/CO2 and CH4/C2H6 gas separation: equilibrium and kinetic studies

被引：135

作者：

Horike, Satoshi ^{[1
]}

Inubushi, Yasutaka ^{[2
]}

Hori, Takashi ^{[2
]}

Fukushima, Tomohiro ^{[1
]}

Kitagawa, Susumu ^{[1
,3
,4
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan

[2] Kuraray Co Ltd, Synth Res Lab, Kurashiki Res Ctr, Kurashiki, Okayama 7100801, Japan

[3] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068501, Japan

[4] Japan Sci & Technol Agcy JST, ERATO Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan

来源：

CHEMICAL SCIENCE | 2012年 / 3卷 / 01期

基金：

日本学术振兴会;

关键词：

METAL-ORGANIC FRAMEWORK; INTERDIGITATED POROUS FRAMEWORK; RATIONAL DESIGN; ADSORPTION; CO2; FLEXIBILITY; SELECTIVITY; PROSPECTS; NETWORKS; CRYSTALS;

D O I：

10.1039/c1sc00591j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gas separation properties for CH4/CO2 and CH4/C2H6 of flexible 2D porous coordination polymers under equilibrium gas conditions and mixed gas flow conditions were investigated and the gas separation efficiencies were optimized by precise tuning of the flexibility in ligand-base solid solution compounds.

引用

页码：116 / 120

页数：5

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