C-C Bond Formation via C-H Activation and C-N Bond Formation via Oxidative Amination Catalyzed by Palladium-Polyoxometalate Nanomaterials Using Dioxygen as the Terminal Oxidant

被引：57

作者：

Chng, Leng Leng ^{[1
]}

Zhang, Jie ^{[1
]}

Yang, Jinhua ^{[1
]}

Amoura, Makhlouf ^{[1
]}

Ying, Jackie Y. ^{[1
]}

机构：

[1] Inst Bioengn & Nanotechnol, The Nanos 138669, Singapore

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 16期

关键词：

C?H activation; heterogeneous catalysis; nanomaterials; palladium; polyoxometalates; COUPLING REACTIONS; DIRECT ARYLATION; PD(II)-CATALYZED OLEFINATION; DIRECT FUNCTIONALIZATION; DIRECT ALKYNYLATION; ROOM-TEMPERATURE; ARENES; COPPER; NANOPARTICLES; SYSTEM;

D O I：

10.1002/adsc.201100362

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An efficient heterogeneous palladium-polyoxometalate catalyst with the formula Pd-H6PV3Mo9O40/C has been successfully developed for carbon-carbon (C?C) bond formation via carbon-hydrogen (C?H) activation and carbon-nitrogen (C?N) bond formation via oxidative amination using oxygen as the terminal oxidant. The coupling processes are simple, and use relatively mild conditions to form the desired products. In addition, less waste is generated as no additional reagents such as organic/inorganic oxidants are required, and water is the only by-product generated.

引用

页码：2988 / 2998

页数：11

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