Stepwise synthesis and properties of a 9,10-dihydro-9,10-diboraanthracene

被引：39

作者：

Agou, Tomohiro ^{[1
,2
]}

Sekine, Masaki ^{[3
]}

Kawashima, Takayuki ^{[3
]}

机构：

[1] Kyoto Univ, Kyoto Univ Pioneering Res Unit Next Generat, Uji 6110011, Japan

[2] Kyoto Univ, Inst Chem Res, Uji 6110011, Japan

[3] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 38期

关键词：

SITE OLEFIN POLYMERIZATION; ELECTRONIC COMMUNICATION; COMPLEXES;

D O I：

10.1016/j.tetlet.2010.07.068

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A stepwise synthetic method for a 9,10-dihydro-9,10-diboraanthracene was developed, and the optical and electrochemical properties as well as the molecular structure of the 9,10-dihydro-9,10-diboraanthracene were elucidated. The 9,10-dihydro-9,10-diboraanthracene exhibited high complexation ability against fluoride ion, and the complexation was accompanied by the enhancement of photoluminescence emission, probably due to intramolecular charge transfer between the two boron atoms. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：5013 / 5015

页数：3

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