Multi-step detection of cyanide ion by a bis(dimesitylboryl)dibenzoazaborine

被引：31

作者：

Agou, Tomohiro ^{[1
]}

Sekine, Masaki ^{[1
]}

Kobayashi, Junji ^{[1
]}

Kawashima, Takayuki ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 23期

关键词：

Dibenzoazaborine; Cyanide ion; Anion sensing; Dimesitylboryl group; OPTICAL-PROPERTIES; FLUORIDE-ION; LEWIS ACIDITY; DIBENZOPHOSPHABORIN; COMPLEXATION; RECOGNITION; AZABORINES; BORON;

D O I：

10.1016/j.jorganchem.2009.07.046

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A bis(dimesitylboryl)dibenzoazaborine formed Lewis acid-base type complexes with up to two cyanide ions in stepwise fashion. The complex formation constants for cyanide ion were larger than those for fluoride ion, despite the higher affinity of fluoride ion to boron atoms than that of cyanide ion. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：3833 / 3836

页数：4

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