Synthesis and reactivity of a bis(dimesitylboryl)azaborine and its fluoride sensing ability

被引：69

作者：

Agou, Tomohiro ^{[1
]}

Sekine, Masaki ^{[1
]}

Kobayashi, Junji ^{[1
]}

Kawashima, Takayuki ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 14期

关键词：

OPTICAL-PROPERTIES; ELECTRONIC COMMUNICATION; ION; AZABORINES; POLYMERS; BORANE;

D O I：

10.1039/b818505k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An azaborine bearing two dimesitylboryl groups on its periphery showed very strong light absorption and moderate photoluminescence emission; the reaction of the title compound with fluoride ion resulted in multi-step fluoride ion complexation on the boron atoms of the dimesitylboryl groups, producing mono- and bisfluoroborates.

引用

页码：1894 / 1896

页数：3

共 16 条

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