Synthesis and reactivity of a bis(dimesitylboryl)azaborine and its fluoride sensing ability

被引：69

作者：

Agou, Tomohiro ^{[1
]}

Sekine, Masaki ^{[1
]}

Kobayashi, Junji ^{[1
]}

Kawashima, Takayuki ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 14期

关键词：

OPTICAL-PROPERTIES; ELECTRONIC COMMUNICATION; ION; AZABORINES; POLYMERS; BORANE;

D O I：

10.1039/b818505k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An azaborine bearing two dimesitylboryl groups on its periphery showed very strong light absorption and moderate photoluminescence emission; the reaction of the title compound with fluoride ion resulted in multi-step fluoride ion complexation on the boron atoms of the dimesitylboryl groups, producing mono- and bisfluoroborates.

引用

页码：1894 / 1896

页数：3

共 16 条

[11] Fluoride ion complexation by a cationic borane in aqueous solution
Lee, Min Hyung
Agou, Tomohiro
Kobayashi, Junji
Kawashima, Takayuki
Gabbai, Francois P.
[J]. CHEMICAL COMMUNICATIONS, 2007, (11) : 1133 - 1135
[12] A bidentate borane as colorimetric fluoride ion sensor
Solé, S
Gabbai, FP
[J]. CHEMICAL COMMUNICATIONS, 2004, (11) : 1284 - 1285
[13] A family of main-chain polymeric Lewis acids:: Synthesis and fluorescent sensing properties of boron-modified polythiophenes
Sundararaman, A
Victor, M
Varughese, R
Jäkle, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (40) : 13748 - 13749
[14] Electronic communication and negative binding cooperativity in diborylated bithiophenes
Sundararaman, Anand
Venkatasubbaiah, Krishnan
Victor, Maria
Zakharov, Lev N.
Rheingold, Arnold L.
Jakle, Frieder
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) : 16554 - 16565
[15] Colorimetric fluoride ion sensing by boron-containing π-electron systems
Yamaguchi, S
Akiyama, S
Tamao, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (46) : 11372 - 11375
[16] Mesitylboron-substituted ladder-type pentaphenylenes:: Charge-transfer, electronic communication, and sensing properties
Zhou, Gang
Baumgarten, Martin
Muellen, Klaus
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (37) : 12477 - 12484

← 1 2 →