Enantioselective fluorescent sensor for dibenzoyl tartrate anion based on chiral binaphthyl derivatives bearing an amino acid unit

被引:43
作者
Qin, Haijuan [1 ]
He, Yongbing [1 ]
Hu, Chenguang [1 ]
Chen, Zhihong [1 ]
Hu, Ling [1 ]
机构
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Hubei, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/j.tetasy.2007.06.027
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The fluorescent photoinduced electron transfer (PET) chemosensors 1-3 based on (S)-1,1'-bi-2-naphthol were designed for their recognition of dibenzoyl tartrate anions. The binding properties for hydroxy acid anions were examined by the fluorescence and H-1 NMR spectra. The results indicated that receptor I exhibit excellent enantioselectivity toward the enantiomers of dibenzoyl tartrate anion. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1769 / 1774
页数:6
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