Luminescence from lanthanide(3+) ions in solution

被引：166

作者：

Dossing, A ^{[1
]}

机构：

[1] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 08期

关键词：

lanthanides; luminescence; fluorescent probes;

D O I：

10.1002/ejic.200401043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An over-view of recent work dealing with luminescence properties in solution of complexes of the lanthanide(3+) ions Nd3+, EU3+, Tb3+, Er3+ and Yb3+ in which an organic chromophore is attached to the metal centre as a sensitizer is given. The various factors that influence the metal-centred luminescence lifetime and intensity are discussed and illustrated with own results and recent literature examples. The VIS emitting metal ions Eu3+ and Tb3+ require sensitizers that absorb light in the UV or near UV range whereas VIS absorbing sensitizers can be used for the NIR emitting ions Nd3+, Er3+ and Yb3+. The latter type of complexes is currently of great interest because of potential applications as luminescent markers in biological systems. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).

引用

页码：1425 / 1434

页数：10

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