Luminescence from lanthanide(3+) ions in solution

被引：166

作者：

Dossing, A ^{[1
]}

机构：

[1] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 08期

关键词：

lanthanides; luminescence; fluorescent probes;

D O I：

10.1002/ejic.200401043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An over-view of recent work dealing with luminescence properties in solution of complexes of the lanthanide(3+) ions Nd3+, EU3+, Tb3+, Er3+ and Yb3+ in which an organic chromophore is attached to the metal centre as a sensitizer is given. The various factors that influence the metal-centred luminescence lifetime and intensity are discussed and illustrated with own results and recent literature examples. The VIS emitting metal ions Eu3+ and Tb3+ require sensitizers that absorb light in the UV or near UV range whereas VIS absorbing sensitizers can be used for the NIR emitting ions Nd3+, Er3+ and Yb3+. The latter type of complexes is currently of great interest because of potential applications as luminescent markers in biological systems. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).

引用

页码：1425 / 1434

页数：10

共 51 条

[11]

Dias LC, 1999, CHEM PHYS LETT, V302, P505, DOI 10.1016/S0009-2614(99)00145-1

[12] Luminescence properties of the europium(III) complex of the octadentate polypyridyl ligand 1,1'-bis[bis(2-pyridylmethyl)aminomethyl]-3,3'-biisoquinoline [J].

Dossing, A .

ACTA CHEMICA SCANDINAVICA, 1997, 51 (10) :981-983

[13] A fluxional lanthanum(III) polypyridyl complex. A nuclear magnetic resonance investigation [J].

Dossing, A ;

Kristensen, SM ;

Toftlund, H ;

Wolny, JA .

ACTA CHEMICA SCANDINAVICA, 1999, 53 (08) :575-580

[14] Dynamics of the excited states of the europium podant, [Eu C36H44N8O5Cl2]Cl•5H2O, in solid state and solutions [J].

Dossing, A ;

Sokolnicki, J ;

Riehl, JP ;

Legendziewicz, J .

JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 341 (1-2) :150-155

[15] Crystal structure, luminescence and other properties of some lanthanide complexes of the polypyridine ligand 6,6'-bis[bis(2-pyridylmethyl) aminomethyl]-2,2'-bipyridine [J].

Dossing, A ;

Toftlund, H ;

Hazell, A ;

Bourassa, J ;

Ford, PC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (03) :335-339

[16]

DOSSING A, IN PRESS

[17] Pyrene-sensitised near-IR luminescence from ytterbium and neodymium complexes [J].

Faulkner, S ;

Carrié, MC ;

Pope, SJA ;

Squire, J ;

Beeby, A ;

Sammes, PG .

DALTON TRANSACTIONS, 2004, (09) :1405-1409

[18] Time-resolved near-IR luminescence from ytterbium and neodymium complexes of the Lehn cryptand [J].

Faulkner, S ;

Beeby, A ;

Carrié, MC ;

Dadabhoy, A ;

Kenwright, AM ;

Sammes, PG .

INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (04) :187-190

[19]

Faulkner S, 2004, COMPREHENSIVE COORDI, P913

[20] Facile preparation and photophysics of near-infrared luminescent lanthanide(III) monoporphyrinate complexes [J].

Foley, TJ ;

Harrison, BS ;

Knefely, AS ;

Abboud, KA ;

Reynolds, JR ;

Schanze, KS ;

Boncella, JM .

INORGANIC CHEMISTRY, 2003, 42 (16) :5023-5032

← 1 2 3 4 5 6 →