Formal synthesis of uvaricin via palladium-mediated double cyclization

被引：45

作者：

Burke, SD ^{[1
]}

Jiang, L ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 12期

关键词：

D O I：

10.1021/ol0160304

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A novel palladium mediated, ligand-controlled double cyclization is reported. The C-2-symmetric diene produced was desymmetrized via Sharpless asymmetric dihydroxylation and was further transformed into a known intermediate in the synthesis of uvaricin.

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页码：1953 / 1955

页数：3

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