A cationic palladium(II) complex-catalyzed Diels-Alder reaction

被引：42

作者：

Oi, S ^{[1
]}

Kashiwagi, K ^{[1
]}

Inoue, Y ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Chem Mat, Sendai, Miyagi 9808579, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(98)01288-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A cationic palladium(II) complex, [PdL2(RCN)(2)](BF4)(2) has been found to catalyze the Diels-Alder reaction of alpha, beta-unsaturated carbonyl compounds with dienes, affording the corresponding cycloadducts in good yields. Excellent enantioselectivity can be achieved in the reaction of N-acryloyloxazolidinone and cyclopentadiene by use of a chiral ligand, BINAP. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：6253 / 6256

页数：4

共 16 条

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[J]. TETRAHEDRON LETTERS, 1996, 37 (35) : 6351 - 6354
[16] (Phosphino-oxazoline)copper(II) complexes as chiral catalysts for enantioselective Diels-Alder reactions
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[J]. TETRAHEDRON LETTERS, 1998, 39 (3-4) : 261 - 264

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