Molecular structure and theoretical studies of (PPh4)2[Bi10Cu10(SPh)24]

被引：19

作者：

Ahlrichs, Reinhart

Eichhoefer, Andreas

Fenske, Dieter

May, Klaus

Sommer, Heino

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

[2] Forschungszentrum Karlsruhe, Inst Nanotechnol, D-76021 Karlsruhe, Germany

[3] Univ Karlsruhe, Inst Phys Chem, D-76131 Karlsruhe, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 43期

关键词：

bismuth; cluster compounds; copper; density functional calculations; sulfur;

D O I：

10.1002/anie.200703325

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Shielded bismuth chains: The reaction of Bi(SPh)3 with CuSPh in the presence of PPh4Cl and PhSSiMe3 produced the title cluster (see picture of the cluster core; Bi red, Cu blue, S yellow). A surprising structural feature is the branched Bi10 chain, which exhibits a structure expected for a neutral and yet unknown klado-Bi 10 cluster. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：8254 / 8257

页数：4

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