A binuclear copper(II) complex containing the pyrazine-2,5-dicarboxylate ligand:: Study of the magnetic exchange through the pyrazine bridge

被引:25
作者
Beobide, G
Castillo, O
García-Couceiro, U
García-Terán, JP
Luque, A
Martínez-Ripoll, M
Román, P
机构
[1] Univ Basque Country, Dept Quim Inorgan, E-48080 Bilbao, Spain
[2] CSIC, Inst Fis & Quim, Grp Cristalog Mol & Biol Estruct, E-28006 Madrid, Spain
关键词
copper; density functional calculations; magnetic properties; N ligands; pyrazine;
D O I
10.1002/ejic.200500119
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The compound [Cu-2(mu-pzdc)(phen)4](NO3)(2)(.)10H(2)O (1; pzdc = pyrazine-2,5-dicarboxylato; phen = 1,10-phenanthroline) has been structurally and magnetically characterised. Theoretical calculations have allowed us to establish a plausible magneto-structural correlation for pyrazine-bridged complexes.
引用
收藏
页码:2586 / 2589
页数:4
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