Molecular design and syntheses of glycopolymers

被引：228

作者：

Okada, M ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Bioagr Sci, Dept Appl Mol Biosci, Chikusa Ku, Nagoya, Aichi 4648601, Japan

来源：

PROGRESS IN POLYMER SCIENCE | 2001年 / 26卷 / 01期

关键词：

glycopolymer; glycodendrimer; glycocluster; biological function; hydrogel; self-assembly; living polymerization;

D O I：

10.1016/S0079-6700(00)00038-1

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Recent progress in precision polymerization has made it possible to design a variety of macromolecules of controlled structure. This review article is concerned with recent topics in the molecular design and syntheses of glycopolymers, particularly focusing on those of well-defined structure. First, linear glycopolymers with controlled molecular weights and molecular weight distributions are described that are produced by various living polymerization techniques developed recently, Secondly, the syntheses of some glycodendrimers and glycoclusters as multivalent ligands are dealt with. Finally, some properties and functions of glycopolymers, such as biological functions, surface-modifier properties, self-assembling properties, etc. are discussed in relation to their structures. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：67 / 104

页数：38

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