Radical aromatic substitution via atom-transfer addition

被引：23

作者：

Byers, JH ^{[1
]}

Campbell, JE ^{[1
]}

Knapp, FH ^{[1
]}

Thissell, JG ^{[1
]}

机构：

[1] Middlebury Coll, Dept Chem & Biochem, Middlebury, VT 05753 USA

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 14期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(99)00304-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New methodology for radical aromatic substitution has been developed involving the addition of electron-deficient radicals to unprotected pyrroles and indole. This non-oxidative process is presumed to be occurring via atom-transfer addition of suitable organoiodides and bromides with subsequent non-radical elimination of HI or HBr, respectively. The process also occurs under stannane-free conditions. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2677 / 2680

页数：4

共 18 条

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