Enthalpy-entropy correlation for hydrogen adsorption on zeolites

被引：76

作者：

Garrone, E. ^{[2
]}

Bonelli, B. ^{[2
]}

Arean, C. Otero ^{[1
]}

机构：

[1] Univ Illes Balears, Dept Quim, Palma de Mallorca 07122, Spain

[2] Politecn Torino, Dipartimento Sci Mat & Ingn Chim, I-10129 Turin, Italy

来源：

CHEMICAL PHYSICS LETTERS | 2008年 / 456卷 / 1-3期

关键词：

D O I：

10.1016/j.cplett.2008.03.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Recently reported values of the enthalpy and entropy changes involved in hydrogen adsorption on several zeolites are analysed, with a view to highlight the observed correlation between Delta H-0 and Delta S-0 and to facilitate understanding. Implications of such a correlation for hydrogen storage on porous solids are also highlighted. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：68 / 70

页数：3

共 44 条

[31] Strategies for hydrogen storage in metal-organic frameworks [J].

Rowsell, JLC ;

Yaghi, OM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4670-4679

[32] The US Department of Energy's National Hydrogen Storage Project: Progress towards meeting hydrogen-powered vehicle requirements [J].

Satyapal, Sunita ;

Petrovic, John ;

Read, Carole ;

Thomas, George ;

Ordaz, Grace .

CATALYSIS TODAY, 2007, 120 (3-4) :246-256

[33] Can Cu+-exchanged zeolites store molecular hydrogen?: An ab-initio periodic study compared with low-temperature FTIR [J].

Solans-Monfort, X ;

Branchadell, V ;

Sodupe, M ;

Zicovich-Wilson, CM ;

Gribov, E ;

Spoto, G ;

Busco, C ;

Ugliengo, P .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (24) :8278-8286

[34] Thermodynamic study on the Langmuir adsorption of various bile salts including taurine and glycine conjugates onto graphite in water [J].

Sugihara, G ;

Shigematsu, DS ;

Nagadome, S ;

Lee, S ;

Sasaki, Y ;

Igimi, H .

LANGMUIR, 2000, 16 (04) :1825-1833

[35] Hydrogen adsorption and storage on porous materials [J].

Thomas, K. Mark .

CATALYSIS TODAY, 2007, 120 (3-4) :389-398

[36] IR-spectroscopic study of the binding isomerism of adsorbed molecules [J].

Tsyganenko, AA ;

Storozhev, PY ;

Areán, CO .

KINETICS AND CATALYSIS, 2004, 45 (04) :530-540

[37] Materials for hydrogen storage:: current research trends and perspectives [J].

van den Berg, Annemieke W. C. ;

Arean, Carlos Otero .

CHEMICAL COMMUNICATIONS, 2008, (06) :668-681

[38] Theoretical maximal storage of hydrogen in zeolitic frameworks [J].

Vitillo, JG ;

Ricchiardi, G ;

Spoto, G ;

Zecchina, A .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2005, 7 (23) :3948-3954

[39] Theoretical characterization of dihydrogen adducts with alkaline cations [J].

Vitillo, JG ;

Damin, A ;

Zecchina, A ;

Ricchiardi, G .

JOURNAL OF CHEMICAL PHYSICS, 2005, 122 (11)

[40] Successful predictions of the residual motion of weakly associated species as a function of the bonding between them [J].

Westwell, MS ;

Searle, MS ;

Klein, J ;

Williams, DH .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (39) :16000-16001

← 1 2 3 4 5 →