Using Pressure to Provoke the Structural Transition of Metal-Organic Frameworks

被引：187

作者：

Beurroies, Isabelle ^{[1
]}

Boulhout, Mohammed ^{[1
]}

Llewellyn, Philip L. ^{[1
]}

Kuchta, Bogdan ^{[1
]}

Ferey, Gerard ^{[2
]}

Serre, Christian ^{[2
]}

Denoyel, Renaud ^{[1
]}

机构：

[1] Univ Aix Marseille I II III, Lab Chim Provence, UMR6264, CNRS, Marseille, France

[2] CNRS, UMR 8180, Inst Lavoisier, Versailles, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 41期

关键词：

energy storage; mercury; metal-organic frameworks; microporous materials; nanostructures; ADSORPTION; MIL-53; SOLIDS; FIELD;

D O I：

10.1002/anie.201003048

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Performance under pressure: Hysteresis of intrusion-extrusion of mercury observed in MIL-53(Cr) particles is interpreted as the transition from large-pore to narrow-pore forms of this metal-organic framework (MOF) material, provoked by the isostatic pressure created by mercury around the porous particles. The observed behavior may be qualitatively explained by asimple energetic model and opens possibilities for applications as dampers or molecular springs. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7526 / 7529

页数：4

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