Sequential Functionalization of Porous Coordination Polymer Crystals

被引：180

作者：

Hirai, Kenji ^{[2
]}

Furukawa, Shuhei ^{[1
,3
]}

Kondo, Mio ^{[3
]}

Uehara, Hiromitsu ^{[1
]}

Sakata, Osami ^{[4
,5
]}

Kitagawa, Susumu ^{[1
,2
,3
]}

机构：

[1] Japan Sci & Technol Agcy JST, ERATO Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[3] Kyoto Univ, Inst Integrated Cell Mat Sci ICeMS, Sakyo Ku, Kyoto 6068501, Japan

[4] JST, CREST, Sayo, Hyogo 6795198, Japan

[5] JST, Japan Synchrotron Res Inst Spring 8, Res & Utilizat Div, Sayo, Hyogo 6795198, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 35期

关键词：

crystal growth; metal-organic frameworks; porous coordination polymers; separation; surface modification; METAL-ORGANIC FRAMEWORK; ZEOLITIC IMIDAZOLATE FRAMEWORKS; GAS-ADSORPTION; SEPARATION; HYDROGEN; LIGAND; CATALYSIS; STORAGE; CAGES;

D O I：

10.1002/anie.201101924

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal extractor: Heterostructured porous coordination polymer crystals fabricated using epitaxial growth have two contradictory porous functions, namely size selectivity and high storage. The crystals not only extract linear petroleum molecules from a mixture with its branched isomer, even at very low concentrations of linear isomer (1 wt %), but also shows improved accumulation of the molecules in its pores. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8057 / 8061

页数：5

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