Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions

被引：421

作者：

Ma, BQ ^{[1
]}

Mulfort, KL ^{[1
]}

Hupp, JT ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 14期

关键词：

D O I：

10.1021/ic050452i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Zn(NO3)(2)-6H(2)O, various dicarboxylic acids, and either 4,4'-bipyridine or N,N'-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide produces a family of anisotropic, mixed-ligand, open-framework compounds featuring paddle-wheel-type coordination of Zn(II) pairs in two dimensions and pyridyl ligand pillaring in the third. Despite 2-fold interpenetration, the compounds contain channels of molecular dimensions and several are permanently microporous, displaying high internal surface areas.

引用

页码：4912 / 4914

页数：3

共 24 条

[1] Design, chirality, and flexibility in nanoporous molecule-based materials
Bradshaw, D
Claridge, JB
Cussen, EJ
Prior, TJ
Rosseinsky, MJ
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) : 273 - 282
[2] A novel class of interpenetrated 3-D network of a dimeric cupric-tetracarboxylate unit
Dalai, S
Mukherjee, PS
Zangrando, E
Lloret, F
Chaudhuri, NR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (06): : 822 - 823
[3] Rhenium-based molecular rectangles as frameworks for ligand-centered mixed valency and optical electron transfer
Dinolfo, PH
Williams, ME
Stern, CL
Hupp, JT
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (40) : 12989 - 13001
[4] Microporous manganese formate: A simple metal-organic porous material with high framework stability and highly selective gas sorption properties
Dybtsev, DN
Chun, H
Yoon, SH
Kim, D
Kim, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) : 32 - 33
[5] Rigid and flexible: A highly porous metal-organic framework with unusual guest-dependent dynamic behavior
Dybtsev, DN
Chun, H
Kim, K
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (38) : 5033 - 5036
[6] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage
Eddaoudi, M
Kim, J
Rosi, N
Vodak, D
Wachter, J
O'Keeffe, M
Yaghi, OM
[J]. SCIENCE, 2002, 295 (5554) : 469 - 472
[7] PREPARATION, CLATHRATION ABILITY, AND CATALYSIS OF A 2-DIMENSIONAL SQUARE NETWORK MATERIAL COMPOSED OF CADMIUM(II) AND 4,4'-BIPYRIDINE
FUJITA, M
KWON, YJ
WASHIZU, S
OGURA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) : 1151 - 1152
[8] Chiral porous coordination networks: rational design and applications in enantioselective processes
Kesanli, B
Lin, WB
[J]. COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) : 305 - 326
[9] Functional porous coordination polymers
Kitagawa, S
Kitaura, R
Noro, S
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) : 2334 - 2375
[10] Rational design and crystal structure determination of a 3-D metal-organic jungle-gym-like open framework
Kitaura, R
Iwahori, F
Matsuda, R
Kitagawa, S
Kubota, Y
Takata, M
Kobayashi, TC
[J]. INORGANIC CHEMISTRY, 2004, 43 (21) : 6522 - 6524

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