Directed assembly metallocyclic supramolecular systems for molecular recognition and chemical sensing

被引：221

作者：

Kumar, Arvind ^{[1
]}

Sun, Shih-Sheng ^{[1
]}

Lees, Alistair J. ^{[2
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2008年 / 252卷 / 8-9期

关键词：

supramolecular chemistry; transition-metal complexes; self-assembly; metallocycles; molecular recognition sensors; chromophore; luminescence;

D O I：

10.1016/j.ccr.2007.07.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In recent years there has been immense interest in metallo-supramolecular architectures and their functional properties. The incorporation of metal centers into supramolecules opens up new possibilities for designing more robust receptors for chemical sensing purposes of ionic and neutral molecules. This review focuses on the advances made in the functional properties of the metallocyclic supramolecules with an emphasis on their potential use in the area of molecular recognition and sensing. We have also tried to cover, to some extent, the use of metallocyclic supramolecules in solid-state thin films for size-selective and chemical composition selectivity of volatile organic guest compounds. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：922 / 939

页数：18

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[51] INTRAMOLECULAR COORDINATION OF BIDENTATE LEWIS-BASES TO A COFACIAL BINUCLEAR COPPER(II) COMPLEX [J].