Excitonic exchange splitting in bulk semiconductors

被引:91
作者
Fu, HX [1 ]
Wang, LW [1 ]
Zunger, A [1 ]
机构
[1] Natl Renewable Energy Lab, Golden, CO 80401 USA
关键词
D O I
10.1103/PhysRevB.59.5568
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present an approach to calculate the excitonic fine-structure splittings due to electron-hole short-range exchange interactions using the local-density approximation pseudopotential method, and apply it to bulk semiconductors CdSe, InP, GaAs, and InAs. Comparing with previous theoretical results, the current calculated splittings agree well with experiments. Furthermore, we provide an approximate relationship between the short-range exchange splitting and the exciton Bohr radius, which can be used to estimate the exchange splitting for other materials. The current calculation indicates Chat a commonly used formula for exchange splitting in quantum dot is not valid. Finally, we find a very large pressure dependence of the exchange splitting: a factor of 4.5 increase as the lattice constant changes by 3.5%. This increase is mainly due to the decrease of the Bohr radius via the char;ge of electron effective mass. [S0163-1829(99)02407-8].
引用
收藏
页码:5568 / 5574
页数:7
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共 55 条
[11]   UNIFIED THEORY OF SYMMETRY-BREAKING EFFECTS ON EXCITONS IN CUBIC AND WURTZITE STRUCTURES [J].
CHO, K .
PHYSICAL REVIEW B, 1976, 14 (10) :4463-4482
[12]   LONGITUDINAL AND TRANSVERSE EXCITONS IN SEMICONDUCTORS [J].
DENISOV, MM ;
MAKAROV, VP .
PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1973, 56 (01) :9-59
[13]   Band-edge exciton in quantum dots of semiconductors with a degenerate valence band: Dark and bright exciton states [J].
Efros, AL ;
Rosen, M ;
Kuno, M ;
Nirmal, M ;
Norris, DJ ;
Bawendi, M .
PHYSICAL REVIEW B, 1996, 54 (07) :4843-4856
[14]   2 DIFFERENT POLARIZABILITIES AND CORRESPONDING CHOICES OF HAMILTONIAN [J].
EHARA, K ;
CHO, K .
SOLID STATE COMMUNICATIONS, 1982, 44 (04) :453-457
[15]   DETERMINATION OF THE ANALYTICAL AND THE NON-ANALYTICAL PART OF THE EXCHANGE INTERACTION OF INP AND GAAS FROM POLARITON SPECTRA IN INTERMEDIATE MAGNETIC-FIELDS [J].
EKARDT, W ;
LOSCH, K ;
BIMBERG, D .
PHYSICAL REVIEW B, 1979, 20 (08) :3303-3314
[16]   Short-range versus long-range electron-hole exchange interactions in semiconductor quantum dots [J].
Franceschetti, A ;
Wang, LW ;
Fu, H ;
Zunger, A .
PHYSICAL REVIEW B, 1998, 58 (20) :13367-13370
[17]   Local-density-derived semiempirical nonlocal pseudopotentials for InP with applications to large quantum dots [J].
Fu, HX ;
Zunger, A .
PHYSICAL REVIEW B, 1997, 55 (03) :1642-1653
[18]   InP quantum dots: Electronic structure, surface effects, and the redshifted emission [J].
Fu, HX ;
Zunger, A .
PHYSICAL REVIEW B, 1997, 56 (03) :1496-1508
[19]   LATTICE VIBRATIONAL PROPERTIES OF HEXAGONAL CDSE [J].
GEICK, R ;
PERRY, CH ;
MITRA, SS .
JOURNAL OF APPLIED PHYSICS, 1966, 37 (05) :1994-&
[20]   ABINITIO CALCULATION OF PHONON DISPERSIONS IN SEMICONDUCTORS [J].
GIANNOZZI, P ;
DE GIRONCOLI, S ;
PAVONE, P ;
BARONI, S .
PHYSICAL REVIEW B, 1991, 43 (09) :7231-7242