Visible-light photoredox catalyzed oxidative Strecker reaction

被引:209
作者
Rueping, Magnus [1 ]
Zhu, Shaoqun [1 ]
Koenigs, Rene M. [1 ]
机构
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
关键词
PHOTOINDUCED ELECTRON-TRANSFER; TERTIARY-AMINES; BIOMIMETIC OXIDATION; HYDROGEN-PEROXIDE; AEROBIC OXIDATION; ANODIC CYANATION; METAL-COMPLEXES; BRONSTED ACIDS; C-C; GENERATION;
D O I
10.1039/c1cc15643h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An aerobic photocatalytic oxidative cyanation of tertiary amines providing valuable alpha-aminonitriles in good to excellent yields was developed. Mild reaction conditions and low catalyst loading are attractive features of the protocol.
引用
收藏
页码:12709 / 12711
页数:3
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