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A Phosphorus/Aluminum-Based Frustrated Lewis Pair as an Ion Pair Receptor: Alkali Metal Hydride Adducts and Phase-Transfer Catalysis
被引:93
作者
:
Appelt, Christian
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Appelt, Christian
[
2
]
Slootweg, J. Chris
论文数:
0
引用数:
0
h-index:
0
机构:
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Slootweg, J. Chris
[
1
]
论文数:
引用数:
h-index:
机构:
Lammertsma, Koop
[
1
]
Uhl, Werner
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Uhl, Werner
[
2
]
机构
:
[1]
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
[2]
Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany
来源
:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
|
2012年
/ 51卷
/ 24期
关键词
:
alkali metals;
density functional calculations;
frustrated Lewis pairs;
hydrides;
silanes;
COMPLEX REDUCING AGENTS;
REDUCTION REACTIONS;
CRYSTAL-STRUCTURES;
LITHIUM HYDRIDE;
COORDINATION;
ACTIVATION;
HYDROGENATION;
DERIVATIVES;
REAGENTS;
LIGANDS;
D O I
:
10.1002/anie.201201855
中图分类号
:
O6 [化学];
学科分类号
:
0703 ;
摘要
:
Helpful frustration: The geminal phosphorus/aluminum-based frustrated Lewis pair (Mes 2P)(tBu 2Al)C-C(H)Ph (Mes=2,4,6-Me 3C 6H 2) forms stable adducts with alkali metal hydrides (LiH, NaH, KH). These molecular hydride complexes display enhanced reactivity, which was demonstrated by the catalytic transformation of chlorotriphenylsilane to the corresponding hydride through a frontside S N2-f@Si pathway. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:5911 / 5914
页数:4
相关论文
共 70 条
[1]
Hydrides of the main-group metals: New variations on an old theme
[J].
Aldridge, S
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
Aldridge, S
;
Downs, AJ
论文数:
0
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0
h-index:
0
机构:
Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
Downs, AJ
.
CHEMICAL REVIEWS,
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[Anonymous], 2009, ANGEW CHEM
[3]
Appelt C., 2011, Angew. Chem, V123, P4011
[4]
Geminal Phosphorus/Aluminum-Based Frustrated Lewis Pairs: C-H versus C≡C Activation and CO2 Fixation
[J].
Appelt, Christian
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Appelt, Christian
;
Westenberg, Hauke
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Westenberg, Hauke
;
论文数:
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h-index:
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Bertini, Federica
;
Ehlers, Andreas W.
论文数:
0
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0
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Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Ehlers, Andreas W.
;
Slootweg, J. Chris
论文数:
0
引用数:
0
h-index:
0
机构:
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Slootweg, J. Chris
;
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Lammertsma, Koop
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Uhl, Werner
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Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Uhl, Werner
.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,
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50
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[5]
A 1,1′-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation
[J].
Bebbington, Magnus W. P.
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机构:
Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France
CNRS, UMR 5069, LHFA, F-31062 Toulouse, France
Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France
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;
Tooze, Robert P.
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Sasol Technol UK, St Andrews KY16 9ST, Fife, Scotland
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Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France
Bourissou, Didier
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Frontside versus Backside SN2 Substitution at Group 14 Atoms: Origin of Reaction Barriers and Reasons for Their Absence
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Bento, A. Patricia
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Vrije Univ Amsterdam, Dept Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Vrije Univ Amsterdam, Amsterdam Ctr Multiscale Modeling, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
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Bickelhaupt, F. Matthias
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Vrije Univ Amsterdam, Dept Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Vrije Univ Amsterdam, Amsterdam Ctr Multiscale Modeling, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Vrije Univ Amsterdam, Dept Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Bickelhaupt, F. Matthias
.
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Nucleophilic substitution at silicon (SN2@Si) via a central reaction barrier
[J].
Bento, A. Patricia
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0
h-index:
0
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Free Univ Amsterdam, Afdeling Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Free Univ Amsterdam, Afdeling Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Bento, A. Patricia
;
Bickelhaupt, F. Matthias
论文数:
0
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h-index:
0
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Free Univ Amsterdam, Afdeling Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Free Univ Amsterdam, Afdeling Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Bickelhaupt, F. Matthias
.
JOURNAL OF ORGANIC CHEMISTRY,
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:2201
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Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide
[J].
Berkefeld, Andreas
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0
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0
h-index:
0
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Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
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Blackwell, JM
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0
机构:
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
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;
Sonmor, ER
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h-index:
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Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
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;
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h-index:
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Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Scoccitti, T
;
Piers, WE
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0
引用数:
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h-index:
0
机构:
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Piers, WE
.
ORGANIC LETTERS,
2000,
2
(24)
:3921
-3923
[10]
POTASSIUM HYDRIDE, A HIGHLY ACTIVE NEW HYDRIDE REAGENT - REACTIVITY, APPLICATIONS, AND TECHNIQUES IN ORGANIC AND ORGANOMETALLIC REACTIONS
[J].
BROWN, CA
论文数:
0
引用数:
0
h-index:
0
机构:
CORNELL UNIV,BAKER CHEM LAB,ITHACA,NY 14850
CORNELL UNIV,BAKER CHEM LAB,ITHACA,NY 14850
BROWN, CA
.
JOURNAL OF ORGANIC CHEMISTRY,
1974,
39
(26)
:3913
-3918
←
1
2
3
4
5
6
7
→
共 70 条
[1]
Hydrides of the main-group metals: New variations on an old theme
[J].
Aldridge, S
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
Aldridge, S
;
Downs, AJ
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
Downs, AJ
.
CHEMICAL REVIEWS,
2001,
101
(11)
:3305
-3365
[2]
[Anonymous], 2009, ANGEW CHEM
[3]
Appelt C., 2011, Angew. Chem, V123, P4011
[4]
Geminal Phosphorus/Aluminum-Based Frustrated Lewis Pairs: C-H versus C≡C Activation and CO2 Fixation
[J].
Appelt, Christian
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Appelt, Christian
;
Westenberg, Hauke
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Westenberg, Hauke
;
论文数:
引用数:
h-index:
机构:
Bertini, Federica
;
Ehlers, Andreas W.
论文数:
0
引用数:
0
h-index:
0
机构:
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Ehlers, Andreas W.
;
Slootweg, J. Chris
论文数:
0
引用数:
0
h-index:
0
机构:
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Slootweg, J. Chris
;
论文数:
引用数:
h-index:
机构:
Lammertsma, Koop
;
Uhl, Werner
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany
Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
Uhl, Werner
.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,
2011,
50
(17)
:3925
-3928
[5]
A 1,1′-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation
[J].
Bebbington, Magnus W. P.
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France
CNRS, UMR 5069, LHFA, F-31062 Toulouse, France
Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France
Bebbington, Magnus W. P.
;
论文数:
引用数:
h-index:
机构:
Bontemps, Sebastien
;
论文数:
引用数:
h-index:
机构:
Bouhadir, Ghenwa
;
Hanton, Martin J.
论文数:
0
引用数:
0
h-index:
0
机构:
Sasol Technol UK, St Andrews KY16 9ST, Fife, Scotland
Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France
Hanton, Martin J.
;
Tooze, Robert P.
论文数:
0
引用数:
0
h-index:
0
机构:
Sasol Technol UK, St Andrews KY16 9ST, Fife, Scotland
Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France
Tooze, Robert P.
;
van Rensburg, Hendrick
论文数:
0
引用数:
0
h-index:
0
机构:
Sasol Technol UK, St Andrews KY16 9ST, Fife, Scotland
Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France
van Rensburg, Hendrick
;
Bourissou, Didier
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France
CNRS, UMR 5069, LHFA, F-31062 Toulouse, France
Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France
Bourissou, Didier
.
NEW JOURNAL OF CHEMISTRY,
2010,
34
(08)
:1556
-1559
[6]
Frontside versus Backside SN2 Substitution at Group 14 Atoms: Origin of Reaction Barriers and Reasons for Their Absence
[J].
Bento, A. Patricia
论文数:
0
引用数:
0
h-index:
0
机构:
Vrije Univ Amsterdam, Dept Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Vrije Univ Amsterdam, Amsterdam Ctr Multiscale Modeling, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Vrije Univ Amsterdam, Dept Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Bento, A. Patricia
;
Bickelhaupt, F. Matthias
论文数:
0
引用数:
0
h-index:
0
机构:
Vrije Univ Amsterdam, Dept Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Vrije Univ Amsterdam, Amsterdam Ctr Multiscale Modeling, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Vrije Univ Amsterdam, Dept Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Bickelhaupt, F. Matthias
.
CHEMISTRY-AN ASIAN JOURNAL,
2008,
3
(10)
:1783
-1792
[7]
Nucleophilic substitution at silicon (SN2@Si) via a central reaction barrier
[J].
Bento, A. Patricia
论文数:
0
引用数:
0
h-index:
0
机构:
Free Univ Amsterdam, Afdeling Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Free Univ Amsterdam, Afdeling Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Bento, A. Patricia
;
Bickelhaupt, F. Matthias
论文数:
0
引用数:
0
h-index:
0
机构:
Free Univ Amsterdam, Afdeling Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Free Univ Amsterdam, Afdeling Theoret Chem, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
Bickelhaupt, F. Matthias
.
JOURNAL OF ORGANIC CHEMISTRY,
2007,
72
(06)
:2201
-2207
[8]
Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide
[J].
Berkefeld, Andreas
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Berkefeld, Andreas
;
Piers, Warren E.
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Piers, Warren E.
;
论文数:
引用数:
h-index:
机构:
Parvez, Masood
.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
2010,
132
(31)
:10660
-10661
[9]
B(C6F5)3-catalyzed hydrosilation of imines via silyliminium intermediates
[J].
Blackwell, JM
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Blackwell, JM
;
Sonmor, ER
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Sonmor, ER
;
Scoccitti, T
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Scoccitti, T
;
Piers, WE
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
Piers, WE
.
ORGANIC LETTERS,
2000,
2
(24)
:3921
-3923
[10]
POTASSIUM HYDRIDE, A HIGHLY ACTIVE NEW HYDRIDE REAGENT - REACTIVITY, APPLICATIONS, AND TECHNIQUES IN ORGANIC AND ORGANOMETALLIC REACTIONS
[J].
BROWN, CA
论文数:
0
引用数:
0
h-index:
0
机构:
CORNELL UNIV,BAKER CHEM LAB,ITHACA,NY 14850
CORNELL UNIV,BAKER CHEM LAB,ITHACA,NY 14850
BROWN, CA
.
JOURNAL OF ORGANIC CHEMISTRY,
1974,
39
(26)
:3913
-3918
←
1
2
3
4
5
6
7
→