New types of Lewis acids used in organic synthesis

被引：40

作者：

Kobayashi, S ^{[1
]}

机构：

[1] Sci Univ Tokyo, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 162, Japan

来源：

PURE AND APPLIED CHEMISTRY | 1998年 / 70卷 / 05期

关键词：

D O I：

10.1351/pac199870051019

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New types of Lewis acids based on group 3 and 4 elements (Sc, Y, La, Zr, and Hf) have unique properties compared to typical Lewis acids. This article describes our recent results on Lewis acid-catalyzed enantioselctive reactions using these elements and their unique properties. Asymmetric versions of Diels-Alder reactions, [2+2] cycloaddition, aza Diels-Alder reactions, 1,3-dipolar cycloaddition, and Mannich-type reactions using chiral rare earth and zirconium catalysts are discussed.

引用

页码：1019 / 1026

页数：8

共 26 条

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