Formation and characterisation of alkoxy derivatives of [60]fullerene

被引：44

作者：

Avent, AG ^{[1
]}

Birkett, PR ^{[1
]}

Darwish, AD ^{[1
]}

Houlton, S ^{[1
]}

Taylor, R ^{[1
]}

Thomson, KST ^{[1
]}

Wei, XW ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2001年 / 05期

关键词：

D O I：

10.1039/b009673n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Heating C60Cl6 with either methanol or propan-2-ol under reflux during 140 h yields 1,4-(MeO)(2)C-60 and 1,4-(iPrO)(2)C-60, respectively, the latter reaction being faster due to the greater nucleophilicity of propan-2-ol. The reaction between C60Cl6 and ROH-NaOR yields C-60(OR)(5)Cl (R=Me, Et) both of which are isostructural with C60Ar5Cl. A by-product of the reaction with ethanol-sodium ethoxide is 1,4-(EtO)(2)C-60 showing that chlorine elimination accompanies substitution; this parallels the formation of 1,4-Ph2C60 from the reaction between C60Cl6 and benzene-FeCl3.

引用

页码：782 / 786

页数：5

共 17 条

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